Vasile POP


28-73 ÎNGLOBAREA DEŞEURILOR PE BAZĂ DE PLUMB ÎN STICLE TELURATE

THE INTEGRATED OF THE LEAD WASTES
IN TELLURATE GLASSES
In this work, we report structural investigations on vanadate-tellurate and borate-tellurate glasses system doped with lead oxide obtained by melt quenching method. The purpose of this paper was i) to integrate of the lead ions in these glasses and ii) to investigate of the structural properties of the obtained glasses in order to possible applications in the wastes recycling.
FTIR spectra analysis suggests that the lead oxide generates the rapidly deformation of the Te-O-Te linkages from [TeO4] structural units. Further the excess of oxygen ions can be accommodated in the host matrix by conversion of some [VO4] structural units into pyro vanadate units. Then, the increase of the lead oxide in the borate-tellurate matrix will produce the intercalation of [PbOn] entities where n=3 and 4.
Based on FTIR results, we found that the increase of the lead oxide in the borate-tellurate network suggests a gradual inclusion of these ions in the host matrix by the intercalation of [PbOn] structural units.
Keywords: bottles of lead telluride-based, IR, recycling
Cuvinte cheie: sticle telurate pe bază de plumb, spectroscopie IR, reciclare

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